全文获取类型
收费全文 | 55358篇 |
免费 | 5188篇 |
国内免费 | 2544篇 |
专业分类
电工技术 | 3350篇 |
技术理论 | 5篇 |
综合类 | 4143篇 |
化学工业 | 9022篇 |
金属工艺 | 3429篇 |
机械仪表 | 3708篇 |
建筑科学 | 4471篇 |
矿业工程 | 1623篇 |
能源动力 | 1577篇 |
轻工业 | 3982篇 |
水利工程 | 1084篇 |
石油天然气 | 3279篇 |
武器工业 | 483篇 |
无线电 | 6118篇 |
一般工业技术 | 6410篇 |
冶金工业 | 2404篇 |
原子能技术 | 558篇 |
自动化技术 | 7444篇 |
出版年
2024年 | 119篇 |
2023年 | 890篇 |
2022年 | 1385篇 |
2021年 | 2191篇 |
2020年 | 1771篇 |
2019年 | 1465篇 |
2018年 | 1612篇 |
2017年 | 1728篇 |
2016年 | 1510篇 |
2015年 | 2264篇 |
2014年 | 2618篇 |
2013年 | 3107篇 |
2012年 | 3439篇 |
2011年 | 3730篇 |
2010年 | 3317篇 |
2009年 | 3242篇 |
2008年 | 3205篇 |
2007年 | 3048篇 |
2006年 | 3228篇 |
2005年 | 2703篇 |
2004年 | 1920篇 |
2003年 | 1965篇 |
2002年 | 2274篇 |
2001年 | 1950篇 |
2000年 | 1407篇 |
1999年 | 1475篇 |
1998年 | 1042篇 |
1997年 | 867篇 |
1996年 | 803篇 |
1995年 | 707篇 |
1994年 | 528篇 |
1993年 | 410篇 |
1992年 | 316篇 |
1991年 | 198篇 |
1990年 | 173篇 |
1989年 | 137篇 |
1988年 | 104篇 |
1987年 | 72篇 |
1986年 | 33篇 |
1985年 | 36篇 |
1984年 | 20篇 |
1983年 | 16篇 |
1982年 | 15篇 |
1981年 | 13篇 |
1980年 | 20篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1959年 | 1篇 |
1953年 | 1篇 |
1951年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
近年来,世界范围内的工业化和城市化进程明显加快,环境污染是全球性的危机。在我国的环保工作开展中,环境影响评价和排污许可是有效的环保工作手段,这两种手段的有效配合,分别从准入和运营的角度来实现了污染的有效控制,虽然环境影响评价在我国实施的时间非常长,但是,排污许可却是近年来才出现的,出现时间的不一致导致二者在衔接和促进的过程中面临着较大的困境。因此,针对这一情况,本文充分探析了环评和排污许可相互衔接和促进的策略。 相似文献
42.
Xu Wang Yujie Zhong Qian Sun Dongqing Qi Fuxue Yan Quangang Xian Dong Wang Kui Du Jingyang Wang 《Journal of the American Ceramic Society》2019,102(4):2176-2186
The microstructure evolution and growth behavior of the Al2O3/Y3Al5O12(YAG)/ZrO2 ternary eutectic ceramics during directional solidification were well investigated. During directional solidification of the Al2O3/YAG/ZrO2 ternary eutectic ceramics, {} Al2O3 paralleled with {001}ZrO2 while they did not parallel with {001}YAG at the same time in the competitive growth stage. All of the interfaces parallel to each other finally. The area percentage of the Al2O3/ZrO2 and YAG/ZrO2 interfaces are 40.4 ± 0.2% and 30.8 ± 0.1%, respectively, higher than that of the Al2O3/YAG (28.8 ± 0.2%). The content of Al2O3 and YAG phases are 39.9% and 41.1%, respectively, almost double of that of ZrO2. The interfaces of Al2O3/ZrO2 and YAG/ZrO2 are shorter and more dispersed than that of the Al2O3/YAG. It was found that the interfacial energy of Al2O3/ZrO2 and YAG/ZrO2 interfaces are lower than that of Al2O3/YAG. It can be concluded that interfacial energy plays a decisive role in affecting the crystallographic orientation and interfaces distribution in the Al2O3/YAG/ZrO2 eutectic since the interfaces of Al2O3/ZrO2 and YAG/ZrO2 with lower interfacial energy can be formed more easily during directional solidification. Therefore, the contents of Al2O3/ZrO2 and YAG/ZrO2 interfaces are higher. This study can provide theoretical guidance for interface design of multi-phase materials. 相似文献
43.
Di An Wei Liu Zhipeng Xie Hezhen Li Xudong Luo Haidong Wu Meipeng Huang Jianwei Liang Zhuo Tian Rongxuan He 《Journal of the American Ceramic Society》2019,102(5):2263-2271
In this study, we developed a unique defect healing method for 3D printed ceramic compact via cold isostatic pressing (CIP) after debinding, and typical features of interlayer interface defects of 3D-printed zirconia compact were characterized and found to be reduced significantly. The characteristic sintering kinetics window and microstructure evolution of the healed sintered bodies were systematically investigated, which was found to be quite different from conventional shaping methods. The three sintering stages are probed by their feature microstructure details such as the mechanically flattening surface at the early sintering stage, the heterogeneous microstructure and high porosity in the interlayer interface region at the middle stage, and the slightly ripple-like structural features combined with the healed interlayer defects at the final stage. The evolution of the pore structure of the healed 3D printed bodies were traced and the mechanical properties such as the Young's modulus, hardness, and fracture toughness were measured to understand the significance of the heal effect. 相似文献
44.
仲春华 《皮革制作与环保科技》2021,(5):34-35
社会经济的快速发展对生态环境造成了较大破坏,并产生了一系列连锁反应,不利于我国可持续发展目标的实现。为此,必须要切实做好环境监测工作。本文从环境监测的概念出发,就现阶段的环境监测现状进行了分析,并在此基础上阐述了环境监测工作未来发展及优化对策,以供参考。 相似文献
45.
46.
Chao Peng Tian Zhang Deliris N Ortiz‐Ortiz Apoorva Vishwakarma Hazel A Barton Abraham Joy 《Polymer International》2019,68(7):1255-1262
Each year, thousands of patients die from antimicrobial‐resistant bacterial infections that fail to respond to conventional antibiotic treatment. Antimicrobial polymers are a promising new method of combating antibiotic‐resistant bacterial infections. We have previously reported the synthesis of a series of narrow‐spectrum peptidomimetic antimicrobial polyurethanes that are effective against Gram‐negative bacteria, such as Escherichia coli; however, these polymers are not effective against Gram‐positive bacteria, such as Staphylococcus aureus. With the aim of understanding the correlation between chemical structure and antibacterial activity, we have subsequently developed three structural variants of these antimicrobial polyurethanes using post‐polymerization modification with decanoic acid and oleic acid. Our results show that such modifications converted the narrow‐spectrum antibacterial activity of these polymers into broad‐spectrum activity against Gram‐positive species such as S. aureus, however, also increasing their toxicity to mammalian cells. Mechanistic studies of bacterial membrane disruption illustrate the differences in antibacterial action between the various polymers. The results demonstrate the challenge of balancing antimicrobial activity and mammalian cell compatibility in the design of antimicrobial polymer compositions. © 2019 Society of Chemical Industry 相似文献
47.
Tian Xie Haixia Zhao Zunhang Lv Guangwen Xie Yan He 《International Journal of Hydrogen Energy》2021,46(1):581-588
This work demonstrates a facile Nb2O5-decorated electrocatalyst to prepare cost-effective Ni–Fe–P–Nb2O5/NF and compared HER & OER performance in alkaline media. The prepared electrocatalyst presented an outstanding electrocatalytic performance towards hydrogen evolution reaction, which required a quite low overpotential of 39.05 mV at the current density of ?10 mA cm?2 in 1 M KOH electrolyte. Moreover, the Ni–Fe–P–Nb2O5/NF catalyst also has excellent oxygen evolution efficiency, which needs only 322 mV to reach the current density of 50 mA cm?2. Furthermore, its electrocatalytic performance towards overall water splitting worked as both cathode and anode achieved a quite low potential of 1.56 V (10 mA cm?2). 相似文献
48.
Wenfei Tian Yi Zheng Weiqun Wang Donghai Wang Michael Tilley Guorong Zhang Zhonghu He Yonghui Li 《Comprehensive Reviews in Food Science and Food Safety》2022,21(3):2274-2308
The health benefits of whole wheat consumption can be partially attributed to wheat's phytochemicals, including phenolic acids, flavonoids, alkylresorcinols, carotenoids, phytosterols, tocopherols, and tocotrienols. It is of increasing interest to produce whole wheat products that are rich in bioactive phytochemicals. This review provides the fundamentals of the chemistry, extraction, and occurrence of wheat phytochemicals and includes critical discussion of several long-lasting issues: (1) the commonly used nomenclature on distribution of wheat phenolic acids, namely, soluble-free, soluble-conjugated, and insoluble-bound phenolic acids; (2) different extraction protocols for wheat phytochemicals; and (3) the chemistry and application of in vitro antioxidant assays. This review further discusses recent advances on the effects of genotypes, environments, field management, and processing techniques including ultrafine grinding, germination, fermentation, enzymatic treatments, thermal treatments, and food processing. These results need to be interpreted with care due to varied sample preparation protocols and limitations of in vitro assays. The bioaccessibility, bioavailability, metabolism, and potential health benefits of wheat phytochemicals are also reviewed. This comprehensive and critical review will benefit scientific researchers in the field of bioactive compounds of cereal grains and also those in the cereal food industry to produce high-quality functional foods. 相似文献
49.
As an industrial solid waste, pyrite cinder exhibited excellent reactivity and cycle stability in chemical looping combustion. Prior to the experiment, oxygen carriers often experienced a high temperature calcination process to stabilize the physico-chemical properties, which presented significant influence on the redox performance of oxygen carriers. However, the effect of calcination temperature on the cyclic reaction performance of pyrite cinder has not been studied in detail. In this work, the effect of calcination temperature on the redox activity and attrition characteristic of pyrite cinder were studied in a fluidized-bed reactor using CH4 as fuel. A series of pyrite cinder samples were prepared by controlling the calcination temperature. The redox activity and attrition rate of the obtained pyrite cinder samples were investigated deeply. The results showed that calcination temperature displayed significant impact on the redox performance of pyrite cinder. Considering CH4 conversion (80%–85%) and attrition resistance, the pyrite cinder calcined at 1050?℃ presented excellent redox properties. In the whole experiment process, the CO2 selectivity of the pyrite cinder samples were not affected by the calcination temperature and were still close to 100%. The results can provide reference for optimizing the calcination temperature of pyrite cinder during chemical looping process. 相似文献
50.
Dan Liu Hongying Yang Jianhui Li Jiaqi Li Yizhe Dong Chuntian Yang Yuting Jin Lekbach Yassir Zhong Li David Hernandez Dake Xu Fuhui Wang Jessica A.Smith 《材料科学技术学报》2021,79(20):101-108
Titanium alloys possess excellent corrosion resistance in marine environments,thus the possibility of their corrosion caused by marine microorganisms is neglected.In this work,microbiologically influenced corrosion (MIC) of TC4 titanium alloy caused by marine Pseudomonas aeruginosa was investigated through electrochemical and surface characterizations during a 14-day immersion test.Results revealed that the unstable surface caused by P.aeruginosa resulted in exposure of Ti2O3 and severe pitting corrosion with maximum pit depth of 5.7 μm after 14 days of incubation.Phenazine-1-carboxy[ate (PCN),secreted by P.aeruginosa,promoted extracellular electron transfer (EET) and accelerated corrosion.Deletion of the phzH gene,which codes for the enzyme that catalyzes PCN production,from the P.aeruginosa genome,resulted in significantly decreased rates of corrosion.These results demonstrate that TC4 titanium alloy is not immune to marine MIC,and EET contributes to the corrosion of TC4 titanium alloy caused by P.aeruginosa. 相似文献